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Hi,

You may want to (pre)order this book: http://blogs.msdn.com/b/obloch/archive/2011/05/25/pre-order-your-windows...

and of course read every article on this blog, keep an eye on the Microsoft Forums dealing with Windows Embedded Compact and read MSDN. Everything you will ever need to know about WEC is online, but if books are your thing than the above link could be worth a try!