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Yes, the error occurs when I use my Client to access the webserver.
I have my Client running on my desktop and my webservice (with the webserver code) on my Windows embedded target.

When I try to access the target just through a web-browser, I see communication occurring on the target side (HelloWorldWebService.exe) and on my web browser (of course I get an error since HTTP GET method is not implemented).

So it seems it's my client side not being able to connect to my target webserver.